MSDS View MSDS : 12345678910111213141516 SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Product Name: KILZ® Original Aerosol MSDS Manufacturer Number: 1024 Manufacturer Name: Masterchem Industries LLC Address: 3135 Old Highway M Imperial, MO 63052-2834 General Phone Number: (636) 942-2510 General Fax Number: (636) 942-3663 Customer Service Phone Number: (800) 325-3552 CHEMTREC: For emergencies in the US, call CHEMTREC: 800-424-9300 Canutec: In Canada, call CANUTEC: (613) 996-6666 (call collect) MSDS Creation Date: 06/26/2006 MSDS Revision Date: 03/09/2008 NFPA 3 1 0 NA HMIS Health Hazard1 Fire Hazard3 REACTIVITY0 Personal Protection x * Chronic Health Effects: SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS#Ingredient Percent Talc, Magnesium silicate hydrate14807-96-6 1 - 5 by weight Silicate, mica12001-26-2 10 - 30 by weight Rutile1317-80-2 5 - 10 by weight Titanium dioxide13463-67-7 10 - 30 by weight Undisclosed/ProprietaryNo data 10 - 30 by weight Xylene1330-20-7 0.1 - 1 by weight Octanes, all isomersNo data 5 - 10 by weight NonanesNo data 10 - 30 by weight Amorphous silica7631-86-9 0.1 - 1 by weight Carbonic acid calcium salt471-34-1 10 - 30 by weight Hydrated aluminum-magnesium silicate12174-11-7 0.1 - 1 by weight VM&P Naphtha/Aliphatic Hydrocarbon8032-32-4 10 - 30 by weight SECTION 3 - HAZARDS IDENTIFICATION Emergency Overview: Flammable. Irritant. Potential Health Effects: Eye: May cause irritation. Skin: May cause irritation. Inhalation: Prolonged or excessive inhalation may cause respiratory tract irritation. Ingestion: Harmful if swallowed. Ingestion can cause nausea, vomiting, diarrhea and gastrointestinal irritation. Chronic Health Effects: Prolonged or repeated contact can result in defatting and drying of the skin, which may result in skin irritation and dermatitis (rash). Repeated or prolonged inhalation may cause toxic effects. Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting. Target Organs: Eyes. Skin. Respiratory system. Digestive system. Central nervous system. Kidney. Aggravation of Pre-Existing Conditions: May aggravate pre-existing respiratory disorders, allergy, eczema, or skin conditions. SECTION 4 - FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for 15 to 20 minutes. Get medical attention, if irritation or symptoms of overexposure persists. Skin Contact: Immediately wash skin with soap and plenty of water. Get medical attention if irritation develops or persists. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested. Provide a glass of water to dilute the material in the stomach. If vomiting occurs naturally, have the person lean forward to reduce the risk of aspiration. SECTION 5 - FIRE FIGHTING MEASURES Flammable Properties: Flammable liquid. Flash Point: <32°F (<0°C) Flash Point Method: Lower Flammable/Explosive Limit: 1% Upper Flammable/Explosive Limit: 7% Fire Fighting Instructions: Flammable. Cool fire-exposed containers using water spray. Extinguishing Media: Use alcohol foam, carbon dioxide, dry chemical, or water fog or spray when fighting fires involving this material. Protective Equipment: As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. Unusual Fire Hazards: Flammable liquid. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to a distant ignition source and flash back. NFPA Ratings: NFPA Flammability: 3 NFPA Health: 1 NFPA Reactivity: 0 NFPA Other: NA SECTION 6 - ACCIDENTAL RELEASE MEASURES Personnel Precautions: Use proper personal protective equipment as listed in section 8. Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways. Spill Cleanup Measures: Remove all sources of ignition. Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable container for disposal. SECTION 7 - HANDLING and STORAGE Handling: Use with adequate ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly closed when not in use. Work Practices: To reduce potential for static discharge, bond and ground containers when transferring material. Special Handling Procedures: Do not reuse containers without proper cleaning or reconditioning. Hygiene Practices: Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or mist. SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. Skin Protection Description: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. EXPOSURE GUIDELINES Talc, Magnesium silicate hydrate : Guideline ACGIH: TLV-TWA: 2 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 Silicate, mica : Guideline ACGIH: TLV-TWA: 3 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 20 mg/m3 Titanium dioxide : Guideline ACGIH: TLV-TWA: 10 mg/m3 Guideline OSHA: OSHA-TWA: 15 mg/m3 Xylene : Guideline ACGIH: TLV-TWA: 100 ppm TLV-STEL: 150 ppm Guideline OSHA: OSHA-TWA: 100 ppm Carbonic acid calcium salt : Guideline ACGIH: TLV-TWA: 5 mg/m3 (Respirable) Guideline OSHA: OSHA-TWA: 5 mg/m3 Respirable VM&P Naphtha/Aliphatic Hydrocarbon : Guideline ACGIH: TLV-TWA: 300 ppm SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Physical State Appearance: Liquid. Flash Point: <32°F (<0°C) Boiling Point: No Data Melting Point: No Data Density: 10 - 12 Lbs./gal. Vapor Density: Greater than 1 (Air = 1). pH: No Data Molecular Formula: Mixture Molecular Weight: Mixture Flash Point: <32°F (<0°C) Flash Point Method: VOC Content: Material VOC: 410 gm/l (Includes Water) Coating VOC.: 410 gm/l (Excludes Water) SECTION 10 - STABILITY and REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Hazardous Polymerization: Not reported. Conditions to Avoid: Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or temperatures below 32 deg. F. Incompatible Materials: Oxidizing agents. Strong acids and alkalis. SECTION 11 - TOXICOLOGICAL INFORMATION RTECS Number: WW2710000 RTECS Number: VV8760000 RTECS Number: VM2940000 Titanium dioxide : RTECS Number: XR2275000 Skin: Skin - Rabbit; Standard Draize Test. : 300 ug/3D; (Intermittent) mild. (RTECS) Ingestion: Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal - hypermotility, diarrhea Gastrointestinal - other changes. (RTECS) Xylene : RTECS Number: ZE2100000 Eye: Eye - Rabbit; Standard Draize Test. : 87 mg; mild. Eye - Rabbit; Standard Draize Test. : 5 mg/24H; severe. (RTECS) Skin: Skin - Rabbit; Standard Draize Test. : 100%; Moderate. Skin - Rabbit; Standard Draize Test. : 500 mg/24H; Moderate. (RTECS) Inhalation: Inhalation. - Rat LC50: 5000 ppm/4H; Details of toxic effects not reported other than lethal dose value. (RTECS) Ingestion: Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes Kidney, Ureter, Bladder - other changes Ingestion - Mouse LD50: 2119 mg/kg; Details of toxic effects not reported other than lethal dose value. (RTECS) Amorphous silica : RTECS Number: EU8655000 Eye: Eye - Rabbit; Standard Draize Test. : 25 mg/24H; mild. (RTECS) Inhalation: Inhalation. - Rat LCLo: 2190 mg/m3/4H; Lungs, Thorax, or Respiration - dyspnea (RTECS) Ingestion: Ingestion - Rat LDLo: 5 gm/kg; Nutritional and Gross Metabolic - other changes (RTECS) RTECS Number: RT6400000 VM&P Naphtha/Aliphatic Hydrocarbon : RTECS Number: OI6180000 Eye: Eye's - Human: 880 ppm/15M; No effects reported. (RTECS) SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: No ecotoxicity data was found for the product. Environmental Fate: No environmental information found for this product. SECTION 13 - DISPOSAL CONSIDERATIONS Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container. Do not store unused product inside the home. For disposal guidance, contact your household refuse collection service, fire department, county or state government environmental control agency. SECTION 14 - TRANSPORT INFORMATION DOT Shipping Name: Aerosol flammable DOT Hazard Class: 2.1 DOT Packing Group: III SECTION 15 - REGULATORY INFORMATION Talc, Magnesium silicate hydrate : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Silicate, mica : TSCA Inventory Status: Not listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Rutile : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Titanium dioxide : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Xylene : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Amorphous silica : TSCA Inventory Status: Listed State Regulations: Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed Carbonic acid calcium salt : Canada DSL: Listed Hydrated aluminum-magnesium silicate : TSCA Inventory Status: Not listed California PROP 65: Listed in California Prop65 list Canada DSL: Not listed VM&P Naphtha/Aliphatic Hydrocarbon : TSCA Inventory Status: Listed State Regulations: Listed in the New Jersey State Right to Know List. Listed in the Pennsylvania State Hazardous Substances List. Canada DSL: Listed SECTION 16 - ADDITIONAL INFORMATION HMIS Fire Hazard: 3 HMIS Health Hazard: 1 HMIS Reactivity: 0 HMIS Personal Protection: x MSDS Creation Date: 06/26/2006 MSDS Revision Date: 03/09/2008 MSDS Revision Notes: Quarterly formula update MSDS Author: Actio Corporation Disclaimer: This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. We shall ensure, so far as is reasonably practicable, that any revision of this Data Sheet is sent to all customers to whom we have directly supplied this substance, but must point out that it is the responsibility of any intermediate supplier to ensure that such revision is passed to the ultimate user. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. Should further information be required, this can be obtained through the sales office whose address is at the top of this data sheet. Trademark: The trademarks, service marks, graphics and logos used on this MSDS are registered or unregistered trademarks of BEHR Process Corporation. All Rights Reserved. Copyright© 1996-2008 Actio Software Corporation. All Rights Reserved.