Compositions of 1-bromopropane, 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane and an organic solvent
Reference Number: N 03-04
Inventors: Thenappan, Alagappan;, Stachura, Leonard Michael; Paonessa, Martin Richard; Cook, Kane David; Shankland, Ian R.
The invention relates to novel compositions comprising effective amounts of 1-bromopropane,
HFE-7100 and at least one organic solvent selected from the group consisting of methanol,
ethanol, 2-propanol, 2-methyl-2-propanol, tetrahydrofuran, nitromethane, and methylene
chloride. In a preferred embodiment, the invention relates to azeotrope-like compositions
comprising from about 50 to about 99 weight percent 1-bromopropane; from about 1 to
about 50 weight percent 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane; and, based on
the total weight of said 1-bromopropane and 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane,
from about 0.2 to about 70 weight percent of at least one organic solvent selected
from the group consisting of methanol, ethanol, 2-propanol, 2-methyl-2-propanol, tetrahydrofuran,
nitromethane, and methylene chloride wherein said compositions boil at from about
35.7.degree. C. to about 53.7.degree. C..+-.2.0.degree. C. at 760 mmHg.
In another embodiment, the invention relates to azeotrope-like compositions comprising from about 89 to about 97 weight percent 1-bromopropane; from about 3 to about 11 weight percent nitromethane; and, based on the total weight of said 1-bromopropane and nitromethane, from about 18 to about 40 weight percent 4-methoxy-1,1,1,2,2,3,3,4,4-nonafluorobutane wherein said compositions boil at about 53.7.degree. C..+-.about 2.0.degree. C. at 760 mmHg.
The 1-bromopropane, HFE-7100 and organic solvent components of the invention are commercially available in pure form and may be obtained readily. For example, HFE-7100 is commercially available from 3M Corporation.
The term "azeotrope-like" is used herein for the preferred mixtures of the invention because in the claimed proportions, the compositions of 1-bromopropane, HFE-7100 and organic solvent are constant boiling or essentially constant boiling. All compositions within the indicated ranges, as well as certain compositions outside the indicated ranges, are azeotrope-like, as defined more particularly below.
From fundamental principles, the thermodynamic state of a fluid is defined by four variables: pressure, temperature, liquid composition, and vapor composition, or P-T-X-Y, respectively. An azeotrope is a unique characteristic of a system of two or more components where X and Y are equal at a stated P and T. In practice, this means that the components cannot be separated during a phase change, and therefore are useful in solvent and aerosol solvent applications.
For the purposes of this discussion, by azeotrope-like composition is intended to mean that the composition behaves like a true azeotrope in terms of its constant boiling characteristics or tendency not to fractionate upon boiling or evaporation. Thus, in such systems, the composition of the vapor formed during evaporation is identical or substantially identical to the original liquid composition. Hence, during boiling or evaporation, the liquid composition, if it changes at all, changes only slightly. This is contrasted with non-azeotrope-like compositions in which the liquid and vapor compositions change substantially during evaporation or condensation.
One way to determine whether a candidate mixture is azeotrope-like within the meaning of this invention, is to distill a sample thereof under conditions (i.e., resolution--number of plates) which would be expected to separate the mixture into its separate components. If the mixture is non an azeotrope or azeotrope-like, the mixture will fractionate, i.e., separate into its various components with the lowest boiling component distilling off first, and so on. If the mixture is azeotrope-like, some finite amount of the first distillation cut will be obtained which contains all of the mixture components and which is constant boiling or behaves as a single substance. This phenomenon cannot occur if the mixture is not azeotrope-like, i.e., if it is not part of an azeotrope system.
It follows from the above that another characteristic of azeotrope-like compositions is that there is a range of compositions containing the same components in varying proportions which are azeotrope-like. All such compositions are intended to be covered by the term azeotrope-like as used herein. As an example, it is well known that at different pressures the composition of a given azeotrope will vary at least slightly as does the boiling point of the composition. Thus, an azeotrope of A and B represents a unique type of relationship but with a variable composition depending on the temperature and/or pressure. As is readily understood by persons skilled in the art, the boiling point of an azeotrope will vary with the pressure.
In the process embodiment of the invention, the compositions of the invention may be used to clean solid surfaces by treating said surfaces with said compositions in any manner well known in the art such as by dipping or use of open or closed vapor degreasing apparatus.
It should be understood that the present compositions may include one or more additional components (such as stabilizers, inhibitors or antioxidants), some of which may form new azeotrope-like compositions. Such additional components typically are added at the expense of 1-bromopropane and in amounts known to one skilled in the art. Preferably, such components are added in an amount of up to about 5 weight percent based on the weight of the 1-bromopropane component, and more preferably in an amount of up to about 5 weight percent based on the total weight of the composition. Any such compositions are considered to be within the scope of the present invention as long as the compositions contain all of the essential components described herein.
Stabilizers typically are added to solvent compositions to inhibit decomposition of the compositions; react with undesirable decomposition products of the compositions; and/or prevent corrosion of metal surfaces. Any combination of conventional stabilizers known to be useful in stabilizing halogenated hydrocarbon solvents may be used in the present invention. Suitable stabilizers include alkanols having 4 to 7 carbon atoms, nitroalkanes having 1 to 3 carbon atoms, 1,2-epoxyalkanes having 2 to 7 carbon atoms, phosphite esters having 12 to 30 carbon atoms, ethers having 3 or 4 carbon atoms, unsaturated compounds having 4 to 6 carbon atoms, acetals having 4 to 7 carbon atoms, ketones having 3 to 5 carbon atoms, and amines having 6 to 8 carbon atoms. Other suitable stabilizers will readily occur to those skilled in the art. See, for example, U.S. Pat. No. 5,665,172.